Nanopi Neo2には、GPIOが24ピンあるので、これを制御するためのライブラリー(WiringNP)をインストールします。
https://github.com/friendlyarm/WiringNP

pi@NanoPi-NEO2:~$ git clone https://github.com/friendlyarm/WiringNP
pi@NanoPi-NEO2:~$ cd WiringNP/
pi@NanoPi-NEO2:~$ chmod 755 build
pi@NanoPi-NEO2:~$ sudo ./build

pi@NanoPi-NEO2:~$ gpio readall
 +-----+-----+----------+------+---+-NanoPi-NEO2--+------+----------+-----+-----+
 | BCM | wPi |   Name   | Mode | V | Physical | V | Mode | Name     | wPi | BCM |
 +-----+-----+----------+------+---+----++----+---+------+----------+-----+-----+
 |     |     |     3.3V |      |   |  1 || 2  |   |      | 5V       |     |     |
 |  12 |   8 |  GPIOA12 | ALT5 | 0 |  3 || 4  |   |      | 5V       |     |     |
 |  11 |   9 |  GPIOA11 | ALT5 | 0 |  5 || 6  |   |      | 0v       |     |     |
 | 203 |   7 |  GPIOG11 |  OUT | 0 |  7 || 8  | 0 | ALT5 | GPIOG6   | 15  | 198 |
 |     |     |       0v |      |   |  9 || 10 | 0 | ALT5 | GPIOG7   | 16  | 199 |
 |   0 |   0 |   GPIOA0 | ALT5 | 0 | 11 || 12 | 0 |  OUT | GPIOA6   | 1   | 6   |
 |   2 |   2 |   GPIOA2 |  OFF | 0 | 13 || 14 |   |      | 0v       |     |     |
 |   3 |   3 |   GPIOA3 |  OFF | 0 | 15 || 16 | 0 |  OFF | GPIOG8   | 4   | 200 |
 |     |     |     3.3v |      |   | 17 || 18 | 0 |  OFF | GPIOG9   | 5   | 201 |
 |  64 |  12 |   GPIOC0 | ALT4 | 0 | 19 || 20 |   |      | 0v       |     |     |
 |  65 |  13 |   GPIOC1 | ALT4 | 0 | 21 || 22 | 0 | ALT5 | GPIOA1   | 6   | 1   |
 |  66 |  14 |   GPIOC2 | ALT4 | 0 | 23 || 24 | 1 |  OUT | GPIOC3   | 10  | 67  |
 +-----+-----+----------+------+---+----++----+---+------+----------+-----+-----+
 | BCM | wPi |   Name   | Mode | V | Physical | V | Mode | Name     | wPi | BCM |
 +-----+-----+----------+------+---+-NanoPi-NEO2--+------+----------+-----+-----+

 +-----+----NanoPi-NEO2 USB/Audio-+----+
 | BCM | wPi |   Name   | Mode | V | Ph |
 +-----+-----+----------+------+---+----+
 |     |     |       5V |      |   | 25 |
 |     |     |  USB-DP1 |      |   | 26 |
 |     |     |  USB-DM1 |      |   | 27 |
 |     |     |  USB-DP2 |      |   | 28 |
 |     |     |  USB-DM2 |      |   | 29 |
 |     |     |    IR-RX |      |   | 30 |
 |  17 |  19 |  GPIOA17 |  OFF | 0 | 31 |
 |     |     |  PCM/I2C |      |   | 32 |
 |     |     |  PCM/I2C |      |   | 33 |
 |     |     |  PCM/I2C |      |   | 34 |
 |     |     |  PCM/I2C |      |   | 35 |
 |     |     |       0V |      |   | 36 |
 +-----+-----+----------+------+---+----+

 +-----+----NanoPi-NEO2 Debug UART-+----+
 | BCM | wPi |   Name   | Mode | V | Ph |
 +-----+-----+----------+------+---+----+
 |   4 |  17 |   GPIOA4 | ALT5 | 0 | 37 |
 |   5 |  18 |   GPIOA5 | ALT5 | 0 | 38 |
 +-----+-----+----------+------+---+----+

Pythonを使う時のライブラリー（RPi.GPIO_NP）をインストールします。
https://github.com/friendlyarm/RPi.GPIO_NP

pi@NanoPi-NEO2:~$ sudo apt-get install python3-dev
pi@NanoPi-NEO2:~$ git clone https://github.com/friendlyarm/RPi.GPIO_NP
pi@NanoPi-NEO2:~$ cd RPi.GPIO_NP
pi@NanoPi-NEO2:~$ sudo python3 setup.py install

vi led.py

#!/usr/bin/env python
import RPi.GPIO as GPIO
import time
PIN_NUM = 7
 
GPIO.setmode(GPIO.BOARD)
GPIO.setup(PIN_NUM,GPIO.OUT)
while True:
        GPIO.output(PIN_NUM,True)
        time.sleep(1)
        GPIO.output(PIN_NUM,False)
        time.sleep(1)
pi@NanoPi-NEO2:~$ sudo python3 led.py

pipのインストール方法

pi@NanoPi-NEO2:~$ wget https://bootstrap.pypa.io/get-pip.py
pi@NanoPi-NEO2:~$ sudo python3 get-pip.py

確認方法

pi@NanoPi-NEO2:~$ pip -V
pip 20.0.2 from /usr/lib/python3/dist-packages/pip (python 3.8)